Search results for "siltaava ligandi"

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Redox-aktiiviset siltaavat ligandit lantanoidikomplekseissa

2017

Redox-aktiiviset siltaavat ligandit on mahdollista hapettaa tai pelkistää suhteellisen pysyviksi radikaaleiksi inertissä atmosfäärissä. Siltaavina ligandeina ne voivat koordinoitua kahden tai useamman metalli-ionin välille. Paramagneettiset siltaavat radikaaliligandit ja lantanoidit ovat lupaavia rakenneosia yksittäismolekyylimagneettien valmistuksessa, sillä radikaalien diffuusit spinorbitaalit voivat peittää lantanoidien 4f-orbitaaleja, jolloin muodostuu voimakas vaihtokytkentä lantanoidin ja radikaalin välille. Lantanoidikompleksien magneettisuus syntyy lantanoidi-ionin elektronien, spin-ratakytkennän ja kidekenttäympäristön vuorovaikutuksista ja siihen vaikuttaa ligandien ja metallin vä…

lantanoiditsiltaava ligandiradikaaliligandiorganometallikemialiganditharvinaiset maametallitorganometalliyhdisteetyksittäismolekyylimagneetti

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